Why are
noble gases in general chemically inert?
Noble gases are generally chemically inert
because.
(i)
All
these elements have stable ns2 np5 configuration. Helium has 1s2 configuration.
(ii)
They
have high ionisation energies and thus have no tendency to lose electrons.
(iii)
They
have zero electron affinity due to which they have no tendency to gain
electrons.
Why ease
to liquefy noble gases increases with increase in atomic number?
The ease of liquefaction of a
gas depends upon the magnitude of attractive forces in its molecules. The
attractive forces in such gases are Vander Waal’s forces and their magnitude
increases with increase in atomic size. Since atomic size increases down the
group, so the ease of liquefaction increases down the group.
Besides
from atmosphere, how is helium obtained?
Helium can also be obtained from
natural gas which contains 2-7% helium. It can also be obtained by heating
cleveite which is an ore of uranium.
Why XeF2
is linear in spite of the fact that Xe is sp3 d hybridised?
The reason is that xe atom has
three lone pairs of electrons and after various repulsions, it acquires linear
structure.
Which
noble gas has the highest boiling point?
Xe is largest in size and the magnitudes
of Vander Waal’s forces in it are maximum.
Hence it has the highest boiling point.
Give
reason which prompted Berthelot to prepare first noble gas compound.
The preparation of first noble
gas compound, XePtCl6 was based on the chance discovery of O2PtCl6.
Bartlett predicted that Xenon should react with PtCl6 to form the
ionic compound because.
(i)
The
ionisation energies of O2 and Xe are comparable
(ii)
The
molecular diameter of O2 and Xe are also similar.
He obtained a crystalline compound of
composition, XePtCl6 on just mixing Xe and PtCl6 at room
temperature.
Xe+PtCl6
(g) Xe+(PtCl6)-(s).
Which
noble gas can be used in botanical gardens?
Neon
lamps are used in botanical gardens and also in green houses. This gas
stimulates growth and is also effective in the formation of chlorophyll.
Which inert gas/gases do not form clatrate
compounds?
The
small sized helium and neon do not form clathrate compounds whereas Ar, Kr and
Xe do form.
Which noble gas can form interstitial compounds
with metals?
Only
helium forms interstitial compounds with metals.
What is the utility of clathrate formation?
Clathrate formation help in the
separation of noble gases.
For,
example, Neon can be separated from Argon, krypton and Xenon by forming
clathrate with quinol. Neon does not form clathrate with quinol.
How will you justify the inclusion of noble
gases in the zero group of the periodic table?
The
long form periodic table is based upon filling of last electrons in various
shell of element. Noble gases due to their ns2 np6 configuration are expected
to be placed in the p-block of the periodic table after the members of the
halogen family. These elements due to their stable configuration do not have
normally any tendency to either lose gain or share electrons. As a result,
there valence is zero and therefore, they are said to belong to zero group of
the periodic table.
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